Abstract

LOVRIC, Milivoj  and  KOMORSKY-LOVRIC, Šebojka. Simulation of Irreversible Electro-oxidation on a Partially Blocked Electrode. Port. Electrochim. Acta [online]. 2020, vol.38, n.3, pp.165-174. ISSN 0872-1904.  https://doi.org/10.4152/pea.202003165.

An irreversible electrode reaction influenced by the reversible potential dependent inhibition is theoretically analysed. The consequence of reactivation of the electrode surface is the continuation of electro-oxidation and the appearance of the second anodic peak in cyclic voltammetry. An indicator of the change of the electrode kinetics caused by the inhibitor is proposed.

Keywords : electrode reactivation; inhibition; partially blocked electrode; simulation.

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